Pi is the sixteenth Greek letter, from Phoenician pe ('mouth'); its value is 80. In the numeral series the next value, 90, belonged to the obsolete letter koppa. Pi's fame is modern and mathematical: since the eighteenth century it has denoted the ratio of a circle's circumference to its diameter, a usage popularised after William Jones and Leonhard Euler; this is a modern convention, not an ancient mystical meaning.
The Greek letters doubled as numerals in the Milesian (alphabetic) system, in which each letter carried a fixed value; the practice of summing a word's letters into a number, called isopsephy, is the Greek counterpart of Hebrew gematria and appears in inscriptions, the Greek Magical Papyri and early Christian texts. Pi's Phoenician ancestry places it in a borrowing whose exact point of contact, somewhere among Al Mina, Cyprus, Crete and Euboea in the Aegean world, is still disputed, though the borrowing itself, conventionally dated to around the 8th century BCE, is agreed to be the ancestor of every European alphabet still in use, including the Latin one covered elsewhere in this atlas.
The Greeks' own contribution was to give vowels dedicated letters of their own, something the consonant-only Phoenician script never did. Its isopsephy value of 80 belongs to the Milesian alphabetic numeral system, which also needed three further, otherwise obsolete letters, digamma (also called stigma), koppa and sampi, to cover every value from 1 up to 900; none of the three survives among the 24 letters in ordinary use today.